Microplastic Removal from Surface Water through Coagulation-Flocculation-Filtration Process
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Department of Civil and Environmental Engineering(MPE), Islamic University of Technology(IUT), Board Bazar, Gazipur-1704, Bangladesh
Abstract
Microplastics (MPs), defined as plastic particles ranging from 1 µm to 5 mm in size, have
emerged as a significant environmental pollutant in recent years. These particles pose serious
risks to aquatic ecosystems and potentially to human health. Wastewater treatment systems face
growing challenges in effectively removing microplastics, with inconsistent removal rates
reported across various treatment facilities. There is currently limited guidance on how to
optimize coagulation-to-filtration processes, including which operational factors most influence
removal efficiency. To address this, a treatment sequence consisting of coagulation, flocculation,
and filtration was developed and tested to evaluate the effectiveness of different coagulants. The
study compared the performance of ferric chloride, polyaluminum chloride (PAC), ferrous
sulfate, and alum. Chloride-based coagulants, particularly PAC, showed the highest effectiveness.
PAC achieved an average removal efficiency of 45.26% (±24.64) for smaller microplastic
particles, with a maximum of 84%, and 61.24% (±26.35) for larger particles, with a maximum of
88%. The study identified pH level and coagulant dosage as the most critical factors influencing
removal success. The findings suggest that combining PAC-based coagulation with precise
control of pH and dosing, followed by treatment through biochar and slow sand filtration (where
applicable), can result in near-complete microplastic removal. This approach offers practical and
scalable solutions, especially for policy implementation and plant upgrades in resource-limited
areas. For two distinct MP sizes, this study went one step further and passed the PAC treated
water separately through a slow sand filter and biochar. In both sizes (0-0.3 mm and 0.3-1.18
mm), biochar outperforms slow sand filters in terms of removal efficiency.
Description
Supervised by
Dr. Md. Rezaul Karim,
Professor,
Department of Civil and Environmental Engineering (CEE)
Islamic University of Technology (IUT)
Board Bazar, Gazipur, Bangladesh
This thesis is submitted in partial fulfillment of the requirements for the degree of Bachelor of Science in Civil and Environmental Engineering, 2025
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Arthur, C., Baker, J., & Bamford, H. (Eds.). (2009). Proceedings of the International Research Workshop on the Occurrence, Effects and Fate of Microplastic Marine Debris (Technical Memorandum NOS-OR&R-30). NOAA Marine Debris https://repository.library.noaa.gov/view/noaa/2509/noaa_2509_DS1.pdf Program. Azizi, N., Meghdad Pirsaheb, N. J. H., & Nabizadeh Nodehi, R. (2023). Removal of most frequent microplastic types and sizes in secondary effluent using Al₂(SO₄)₃: Choosing variables by a fuzzy Delphi method. Scientific Reports, 13(1). https://doi.org/10.1038/s41598-023-47803-4 Azizi, N., Pirsaheb, M., Jaafarzadeh, N., & Nabizadeh Nodehi, R. (2023). Microplastics removal from aquatic environment by coagulation: Selecting the best coagulant based on variables determined from a systematic https://doi.org/10.1016/j.heliyon.2023.e15664 review. Heliyon, 9(5), e15664. Chen, Z., Liu, J., Chen, C., & Huang, Z. (2020). Sedimentation of nanoplastics from water with Ca/Al dual flocculants: Characterization, interface reaction, effects of pH and ion ratios. Chemosphere, 252, 126450. https://doi.org/10.1016/j.chemosphere.2020.126450 Cherniak, S. L., Almuhtaram, H., McKie, M. J., Hermabessiere, L., Yuan, C., Rochman, C. M., & Andrews, R. C. (2022). Conventional and biological treatment for the removal of microplastics from drinking water. Chemosphere, https://doi.org/10.1016/j.chemosphere.2021.132587 288(Pt 2), 132587. Cristaldi, A., Fiore, M., Zuccarello, P., Oliveri Conti, G., Grasso, A., Nicolosi, I., Copat, C., & Ferrante, M. (2020). Efficiency of Wastewater Treatment Plants (WWTPs) for Microplastic Removal: A Systematic Review. International Journal of Environmental Research and Public Health, 17(21). https://doi.org/10.3390/ijerph17218014 28 Eydi Gabrabad, M., Bonyadi, Z., Davoudi, M., & Barikbin, B.(2024). Microplastic removal using okra (Abelmoschus esculentus) seed from aqueous solutions. Applied Water Science, 14(10), 217. https://doi.org/10.1007/s13201-024-02249-5 El Gamal, M., Mousa, H. A., El-Naas, M. H., Zacharia, R., & Judd, S. (2018). Bio-regeneration of activated carbon: A comprehensive review. Separation and Purification Technology, 197, 345–359. https://doi.org/10.1016/j.seppur.2017.10.030 Eriksen, N., Maximenko, M., Thiel, A., Cummins, G., Lattin, S., Wilson, J., Hafner, Zellers, S., & Rifman, S. (2013). Plastic pollution in the South Pacific A., subtropical gyre. Marine Pollution Bulletin, 68, 71–76. https://doi.org/10.1016/j.marpolbul.2012.12.021 Esfandiari, A., & Mowla, D. (2021). Investigation of microplastic removal from greywater by coagulation and dissolved air flotation. Process Safety and Environmental Protection, 151, 341–354. https://doi.org/10.1016/j.psep.2021.05.043 Fadlilah, L. I., & Yekti Bagastyo, A. (2024). Coagulation of Wastewater Containing Polyethylene Terephthalate (PET) Microplastics by Using Ferric Chloride, Aluminum Sulfate and Aluminum Chlorohydrate: A Comparative Study. International Journal Multidisciplinary Research and Analysis, 07(07). i07-40 https://doi.org/10.47191/ijmra/v7 of Fatema, K., Rahman, T., Islam, M. J., Sumon, K. A., Uddin, M. H., Hasan, S. J., & Rashid, H. (2023). Microplastics pollution in the river Karnaphuli: A preliminary study on a tidal confluence river in the southeast coast of Bangladesh. Environmental Science and Pollution Research, 30(13), 38853–38868. https://doi.org/10.1007/s11356-023-27700-1 Hidayaturrahman, H., & Lee, T. G. (2019). A study on characteristics of microplastic in wastewater of South Korea: Identification, quantification, and fate of microplastics during treatment process. Marine Pollution Bulletin, https://doi.org/10.1016/j.marpolbul.2019.06.071 146, 696–702. Hossain, M. J., AftabUddin, S., Akhter, F., Nusrat, N., Rahaman, A., Sikder, M. N. A., & Zhang, J. (2022). Surface water, sediment, and biota: The first multi- compartment analysis 29 of microplastics in the Karnafully River, Bangladesh. Marine Pollution Bulletin, 180, 113820. https://doi.org/10.1016/j.marpolbul.2022.113820 Islam, M. S., Islam, Z., & Hasan, M. R. (2022). Pervasiveness and characteristics of microplastics in surface water and sediment of the Buriganga River, Bangladesh. Chemosphere, 307, 135945. https://doi.org/10.1016/j.chemosphere.2022.135945 Jahan, I., Chowdhury, G., Baquero, A. O., Couetard, N., Hossain, M. A., Mian, S., & M. M.(2024). Microplastics pollution in the Surma river, Bangladesh: A Iqbal, rising hazard to upstream water quality and aquatic life. Journal of Environmental Management 360, 121117. https://doi.org/10.1016/j.jenvman.2024.121117 Jaikumar, G., Brun, N. R., Vijver, M. G., & Bosker, T. (2019). Reproductive toxicity primary and secondary microplastics to three cladocerans during chronic Environmental Pollution, 249, 638–646. of exposure. https://doi.org/10.1016/j.envpol.2019.03.017 Jones, N. R., de Jersey, A. M., Lavers, J. L., Rodemann, T., & Rivers-Auty, J. (2024). Identifying laboratory sources of microplastic and nanoplastic contamination from the air, water, and consumables. Journal of Hazardous Materials, 465, https://doi.org/10.1016/j.jhazmat.2023.133276 133276. Khan, M. B., Urmy, S. Y., Setu, S., Kanta, A. H., Gautam, S., Eti, S. A., & Baten, M. A. (2023). Abundance, distribution and composition of microplastics in sediment and fish species from an urban river of Bangladesh. Science of the Total Environment, 885, 163876. https://doi.org/10.1016/j.scitotenv.2023.163876 Koelmans, A. A., Mohamed Nor, N. H., Hermsen, E., Kooi, M., Mintenig, S. M., & France, J. (2019). Microplastics in freshwaters and drinking water: Critical review assessment of data quality. Water Res, 155, De and 410-422. https://doi.org/10.1016/j.watres.2019.02.054 Kovačić, M., Tomić, A., Tonković, S., Pulitika, A., Papac Zjačić, J., Katančić, Z., Genorio, B., Kušić, H., & Lončarić Božić, A. (2024). Pristine and UV-weathered PET microplastics as 30 water contaminants: Appraising the potential of the Fenton process for effective remediation. Processes, 12(4). https://doi.org/10.3390/pr12040844 Li, C., Busquets, R., & Campos, L. C. (2024). Enhancing microplastic removal from water using coagulant aids. https://doi.org/10.1016/j.chemosphere.2024.143145 Chemosphere, 364, Lin, J.-Y., Lee, I., Tzeng, J.-H., Li, W., Kim, H., & Huang, C.-P. (2023). The surface of freshly synthesized microplastic particles in simple electrolyte. natural 143145. acidity Colloids and Surfaces A: Physicochemical and Engineering Aspects, 675, https://doi.org/10.1016/j.colsurfa.2023.132000 132000. Liu, J., Zhu, Y., Tao, Y., Zhang, Y., Li, A., Li, T., Sang, M., & Zhang, C. (2013). Freshwater microalgae harvested via flocculation induced by pH decrease. Biotechnology for Biofuels 6, 98. https://doi.org/10.1186/1754-6834-6-98 Liu, W., Zhang, J., Liu, H., Guo, X., Zhang, X., Yao, X., Cao, Z., & Zhang, T. (2021). A review of the removal of microplastics in global wastewater treatment plants: Characteristics and mechanisms. Environ Int, 146, 106277. https://doi.org/10.1016/j.envint.2020.106277 Lu, D., Song, Y., Yang, Z., & Li, H. (2024). Research progress and perspective on sludge anaerobic digestion technology: A bibliometric analysis. Water Sci Technol, 89(9), 2311 2325. https://doi.org/10.2166/wst.2024.121 Luu, T. T., Truong, D. Q., Nguyen, V. N., Jeong, S., Nguyen, T. T. T., Do, V. M., Vigneswaran, S., & Nguyen, T. V. (2025). Removal of microplastics from laundry wastewater using coagulation and membrane combination: A laboratory-scale study. Membranes (Basel), 15(2). https://doi.org/10.3390/membranes15020047 Maslamani, S., Palsamy, K., Baskaran, T., & Sureshkumar, M. (2024). Impacts of microplastic pollution on the environment and its effective treatment– A review. Water, Air, & Soil Pollution, 235, 10.1007/s11270-024-07301-3. https://doi.org/10.1007/s11270-024-07301-3 31 Mercy, F. T., Alam, A. R., & Akbor, M. A. (2023). Abundance and characteristics of microplastics in major urban lakes of Dhaka, Bangladesh. Heliyon, 9(4), e15176. https://doi.org/10.1016/j.heliyon.2023.e15176 Novotna, K., Cermakova, L., Pivokonska, L., Cajthaml, T., Pivokonsky, M. 2019. Microplastics in drinking water treatment, current knowledge and research needs. Science of the Total Environment 667, 730–740. https://doi.org/10.1016/j.scitotenv.2019.02.431 Ogwu, M., Babafemi, O., Dare, A., Ovuru, K., & Iyiola, A. (2024). Traditional and conventional water treatment methods: A sustainable approach. In Sustainable Water Treatment Technologies (Chapter 15). Springer. https://doi.org/10.1007/978-981-97-4966-9_15 Park, H.-J., Oh, M.-J., Kim, P.-G., Kim, G., Jeong, D.-H., Ju, B.-K., Lee, W.-S., Chung, H.-M., Kang, H.-J., & Kwon, J.-H. (2020). National reconnaissance survey of microplastics in municipal wastewater treatment plants in Korea. Environmental Technology, 54, 1503–1512. https://doi.org/10.1021/acs.est.9b06682 Science & Parsa, M. M., Pourfakhar, H., & Baghdadi, M. (2020). Application of graphene oxide nanosheets in the coagulation-flocculation process for removal of Total Organic Carbon (TOC) from surface water. Journal of Water Process Engineering, https://doi.org/10.1016/j.jwpe.2020.101367 37. Peng, G., Xu, P., Zhu, B., Bai, M., Li, D., 2018. Microplastics in freshwater river sediments in Shanghai, China: a case study of risk assessment in mega-cities. Environ. Pollut. 234, 448–456. https://doi.org/10.1016/j.envpol.2017.11.034. Rahman, S. M. A., Robin, G. S., Momotaj, M., Uddin, J., & Siddique, M. A. M. (2020). Occurrence and spatial distribution of microplastics in beach sediments of Cox’s Bazar, Bangladesh. Marine Pollution Bulletin, 160, 111587. https://doi.org/10.1016/j.marpolbul.2020.111587 Rajala, K., Grönfors, O., Hesampour, M., & Mikola, A. (2020). Removal of microplastics from secondary wastewater treatment plant effluent by coagulation/flocculation with iron, aluminum and polyamine-based chemicals. Water https://doi.org/10.1016/j.watres.2020.116045 Research, 183, 116045. 32 Rakib, M., Jahan, R., Al Nahian, S., Alfonso, M. B., Khandaker, M. U., Enyoh, C. E., & Islam, M. A. (2021). Microplastics pollution in salt pans from the Maheshkhali Channel, Bangladesh. Scientific Reports, 11, 24507. https://doi.org/10.1038/s41598-021-02457-y Tajwar, M., Shreya, S. S., Gazi, M. Y., Hasan, M., & Saha, S. K. (2022). Microplastic contamination in the sediments of the Saint Martin’s Island, Bangladesh. Regional Studies in Marine Science, 53, 102401. https://doi.org/10.1016/j.rsma.2022.102401 Tong, M., He, L., Rong, H., Li, M., & Kim, H. (2020). Transport behaviors of plastic particles in saturated quartz sand without and with biochar/Fe₃O₄-biochar amendment. Water Research, 169, 115284. https://doi.org/10.1016/j.watres.2019.115284 Uddin, S., Fowler, S. W., & Behbehani, M. (2020). An assessment of microplastic into the aquatic environment from wastewater streams. Marine Pollution inputs Bulletin, 160, 111538. https://doi.org/10.1016/j.marpolbul.2020.111538 Urmy, S. Y., Setu, S., Kanta, A. H., Gautam, S., Eti, S. A., & Baten, M. A. (2023). Abundance, distribution and composition of microplastics in sediment and fish species from an urban river of Bangladesh. Science of the Total https://doi.org/10.1016/j.scitotenv.2023.163876 Environment, 885, 163876. Wang, F., Wang, B., Duan, L., Zhang, Y., Zhou, Y., Sui, Q., Xu, D., Qu, H., & Yu, G. (2020). Occurrence and distribution of microplastics in domestic, industrial, agricultural and aquacultural wastewater sources: A case study in Changzhou, China. Water Research, 182, 115956. https://doi.org/10.1016/j.watres.2020.115956 Wiśniowska, E., Moraczewska-Majkut, K., Nocoń, W., & Popenda, A. (2024). Microplastics removal from natural surface water by coagulation process. Desalination and Treatment, 319. https://doi.org/10.1016/j.dwt.2024.100462 Yin, L., Wen, X., Huang, D., Zhou, Z., Xiao, R., Du, L., Su, H., Wang, K., Tian, Q., Z., Gao, L., 2022. Abundance, characteristics, and distribution of Water Tang, microplastics in the Xiangjiang river, China. https://doi.org/10.1016/j.gr.2022.01.019. Gondwana Res. 107, 123–133. 33 Zhang, Y., Zhao, J., Liu, Z., Tian, S., Lu, J., Mu, R., & Yuan, H. (2021). Coagulation removal of microplastics from wastewater by magnetic magnesium hydroxide and PAM. Journal of Water Process Engineering, 43, 102250. https://doi.org/10.1016/j.jwpe.2021.102250 Zhang, Y., Zhou, G., Yue, J., Xing, X., Yang, Z., Wang, X., Wang, Q., & Zhang, J. (2021). Enhanced removal of polyethylene terephthalate microplastics through polyaluminum chloride coagulation with three typical coagulant aids. Science of the Total Environment, 800, 149589. https://doi.org/10.1016/j.scitotenv.2021.149589 Ziembowicz, S., Kida, M., & Koszelnik, P. (2023). Elimination of a mixture of microplastics using conventional and detergent-assisted coagulation. Materials (Basel), 16(11), 4070. https://doi.org/10.3390/ma16114070 Zhou, G., Wang, Q., Li, J., Li, Q., Xu, H., Ye, Q., Wang, Y., Shu, S., & Zhang, J. (2021). Removal of polystyrene and polyethylene microplastics using PAC and FeCl₃ coagulation: Performance and mechanism. Science of the Total 141837. https://doi.org/10.1016/j.scitotenv.2021.141837 Environment, 752, Zhou, X., Zhao, Y., Pang, G., Jia, X., Song, Y., Guo, A., Wang, A., Zhang, S., & Ji, M. (2022). Microplastic abundance, characteristics and removal in large-scale multi-stage constructed wetlands for effluent polishing in northern China. Chemical Engineering Journal, 430, 132752. https://doi.org/10.1016/j.cej.2021.132752
